Work residence permit process starts in the country of the applicant through the Greek Consulate after appropriate supporting documents are shown, and not with the extension of a tourist visa. The tourist visa may under certain conditions be extended for an equal period of time but it does not serve the purpose you mentioned.
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How can I change from a tourist visa to a residency visa in Greece?
How can I as a Filipino be allowed to stay in Greece on a tourist visa for 90 days and find a work there? Then, how can I extend my stay or change my visa so I can migrate to Greece when i got the job?