You cannot apply for the visa while you are in Italy, you will need to go back to your country or residency. The Digital Nomad Visa is quite difficult to obtain, see red flags
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How can I apply for the Italy digital nomad visas?
Is the Italy nomad visa a real option? Is it better to travel to Italy as a tourist and apply from there, or should I do it from a consulate?
Answers
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It is not possible to apply for a digital nomad visa while in Italy: you should lodge your application, complete with all required supporting documents, at the Italian Consulate which is competent based on the place in which you reside.